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Butanol

 
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rebelman



Joined: 25 Apr 2006
Posts: 31
Location: North Carolina

PostPosted: Wed Oct 11, 2006 5:29 pm    Post subject: Butanol Reply with quote

I know this forum is supposed to be for ethanol but I think that all biofuels are important to lessen the dependence on forgein oil. I wanted to know if anyone in the forum has heard of the biofuel being developed by BP and Dupont. It's called Biobutanol and it is supposed to replace gasoline drop for drop but still burn clean and improve performance.
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Revision



Joined: 14 Sep 2005
Posts: 194
Location: Carol Stream, IL

PostPosted: Wed Oct 11, 2006 10:16 pm    Post subject: Reply with quote

There is a news thread about it somewhere. There is also a discussion going on about it in the greencarcongress.. It is suppose to be less octane than E85 and there seems to be a conversion cost issue. ie it is more expensive than E85.

There was some talk about using biobutanol to replace MTBE, but it looks like the oil refiners are happy to just use 10% ethanol.

IIRC biobutanol is made from biostocks and is a 4 hydrocarbon chain like gasoline which is why it runs the same AFR. No one is talking about the exact method used to convert ethanol stocks into biobutanol. Rolling Eyes

If someone knows anything more, please post.
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1outlaw



Joined: 15 Feb 2006
Posts: 89
Location: Central Wisconsin

PostPosted: Wed Oct 11, 2006 10:38 pm    Post subject: Reply with quote

Bp plans to make Butanol from sugar beets by the process they are working with Dupont on. Butanol claims are similar mileage to gasoline and not have an affinity for moisture absorption which would allow it to ba shipped via pipeline. However- it is unlike ethanol in that it is very toxic but I suppose if you put it in gas- will that be a concern??? MTBE (a chemical alcohol) was a problem that way and one does have to be careful handling Methanol too.
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hsd0006



Joined: 19 Jul 2007
Posts: 9
Location: Western Illinois

PostPosted: Thu Jul 19, 2007 12:54 pm    Post subject: Reply with quote

I've read up on biobutanol. It seems like a dream come true until you look at the effects colder weather has on it. It gels up a little like biodiesel. In my opinion, a good end-game liquid fuel solution would be something like 50% ethanol and 50% biobutanol. The ethanol will keep it from freezing up.
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Alcohol



Joined: 17 Apr 2007
Posts: 634
Location: Central Wisconsin

PostPosted: Thu Jul 19, 2007 8:45 pm    Post subject: Reply with quote

hsd0006 wrote:
I've read up on biobutanol. It seems like a dream come true until you look at the effects colder weather has on it. It gels up a little like biodiesel. In my opinion, a good end-game liquid fuel solution would be something like 50% ethanol and 50% biobutanol. The ethanol will keep it from freezing up.


Thats good to know hsd0006- do you have a link on the cold temp issue for biobutanol?
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hsd0006



Joined: 19 Jul 2007
Posts: 9
Location: Western Illinois

PostPosted: Fri Jul 20, 2007 10:42 am    Post subject: Reply with quote

Alcohol wrote:
hsd0006 wrote:
I've read up on biobutanol. It seems like a dream come true until you look at the effects colder weather has on it. It gels up a little like biodiesel. In my opinion, a good end-game liquid fuel solution would be something like 50% ethanol and 50% biobutanol. The ethanol will keep it from freezing up.


Thats good to know hsd0006- do you have a link on the cold temp issue for biobutanol?


Here's one:
http://en.wikipedia.org/wiki/Biobutanol
Scroll to where it says octane rating.

http://money.cnn.com/2007/04/02/news/economy/biobutanol/index.htm
This article really doesn't say anything about the gelling issue, but it does note that biobutanol distillation is more energy intensive and a breakthrough enzyme is needed to make it. While cellulosic ethanol can be produced from gasified biomass.
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Alcohol



Joined: 17 Apr 2007
Posts: 634
Location: Central Wisconsin

PostPosted: Fri Jul 20, 2007 11:33 am    Post subject: Reply with quote

Thanks hsd0006- I wonder if the Butanol octane rating is for 1 butanol or t butanol. The MON (motor) number is not impressive. If you do the RON+MON/2= (AON) formula you only get 87. I is my understanding that a low MON # will make the AON dececeptive and can lead to preignition.
If this is the correct octane #, then east of the Rockies- oil companies would need to use a higher octane (sometimes more expensive) 87 base fuel than the 85 suboctane they sometimes use.
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mtbottle



Joined: 14 Jan 2006
Posts: 46
Location: West Virgnia

PostPosted: Sat Jul 28, 2007 4:08 am    Post subject: butanol Reply with quote

Butanol does have some possibilities, but there is a huge hurdle. Distilling butanol is not near as efficient as ethanol. Due to its characteristics it will kill off the yeast culture at much lower yields as ethanol. About 1/2 the concentration. That makes it much more expensive to make.
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Fredster



Joined: 20 Nov 2006
Posts: 111

PostPosted: Sat Jul 28, 2007 1:36 pm    Post subject: Reply with quote

Alcohol wrote:
Thanks hsd0006- I wonder if the Butanol octane rating is for 1 butanol or t butanol. The MON (motor) number is not impressive. If you do the RON+MON/2= (AON) formula you only get 87. I is my understanding that a low MON # will make the AON dececeptive and can lead to preignition.
If this is the correct octane #, then east of the Rockies- oil companies would need to use a higher octane (sometimes more expensive) 87 base fuel than the 85 suboctane they sometimes use.


what are you sayin that ron is overestimated in the chemical tests compared to mon, (motor octane number, research octane number, average of both is the octane number at the pump... simply put you do the chemical test and the engine test)
So that the aon is actually lower for the engine than actually really is ?

or are you just a fan of mon only tests ?
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