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O2 sensors and E85

 
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pete



Joined: 11 Oct 2005
Posts: 2
Location: Phoenix AZ

PostPosted: Tue Oct 11, 2005 6:19 pm    Post subject: O2 sensors and E85 Reply with quote

Hello all.
I'm in the process of building a performance EFI system for the Ford 302 V8. My business partner brought up the idea of modifying a system to run E-85. My biggest question is with the O2 sensor. Our computer is fully user controlled but has the ability to use the O2 sensor for mixture correction. Is there any difference in the O2 content in the exhaust when burning gas at stoich and E-85 at stoich?

We also have the ability to use a Wide Band O2 but again I'm unclear what it will tell me when running E85.

The computer allows you to upload it's configuration to a laptop or palm and then download a different set of parameters. We would like to develop two sets of parameters for the computer. One for E85 and one for gas. This way the owner could simply download the gas configuration when he/she can't get E85.
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hotrod



Joined: 19 Apr 2005
Posts: 872
Location: Colorado

PostPosted: Tue Oct 11, 2005 9:36 pm    Post subject: Reply with quote

No your O2 sensor is a "lambda sensor" and only cares about how much excess oxygen is present.

Stoich mixtures always return a lambda value of 1.

In closed loop my WRX has no issues at all with widely varying E85 percentages in the tank. It quickly sees the need to modify fuel trims and within a very short time you can watch the fuel trims change if you have an OBDII scanner hooked up.

The only caution is that when running the wideband if possible set it to report mixtures in lambda or equivalence ratio (which ever you prefer) so that you get valid numbers when mixing different types of fuels.

Larry
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pete



Joined: 11 Oct 2005
Posts: 2
Location: Phoenix AZ

PostPosted: Wed Oct 12, 2005 4:41 pm    Post subject: Reply with quote

Thanks. That's what I wanted to know.
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jachristner



Joined: 12 Oct 2005
Posts: 64
Location: Kokomo, IN

PostPosted: Wed Oct 12, 2005 6:09 pm    Post subject: I'm confused Reply with quote

What are the differences between a normal and a wideband O2 sensor?

Are there advantages or disadvantages to either one in a car being converted to run on both full Gasoline and E85?
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hotrod



Joined: 19 Apr 2005
Posts: 872
Location: Colorado

PostPosted: Wed Oct 12, 2005 11:24 pm    Post subject: Reply with quote

The common O2 sensor you find in most cars for emissions control and the cheap AFR gauges is only useful very close to a stochimetric mixture.

It switchs its output very drastically with very small changes in AFR. Pretty much tells you only you are rich of stoich or lean of stoich, but of very limited use to see small changes in AFR.


A wideband sensor is designed with a much more uniform response so it can see mixture changes from very rich (like 10:1 to very lean like 16:1)

Serious tuning demands use of the wide band sensor.

Larry
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jachristner



Joined: 12 Oct 2005
Posts: 64
Location: Kokomo, IN

PostPosted: Sat Oct 15, 2005 12:43 am    Post subject: Reply with quote

From what I could find on the internet explaining how the sensor works, I understood that it wasn't reporting the AFR of the engine but rather the percentage of gaseous O2 in the exhaust stream. If that's the case, the sensor would only know if the engine is running lean and maybe a rough estimate of how much, but not much else as a rich condition would most likely leave no or little O2.
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B.A.Bowling



Joined: 15 Feb 2006
Posts: 6
Location: Baltimore, MD

PostPosted: Wed Feb 15, 2006 9:46 pm    Post subject: Reply with quote

I will add a bit to this thread....

A narrowband O2 sensor will show a point of stoichiometric the same for E85, gasoline, or any blend. In other words, a voltage of 0.45 volts from the sensor (Nernst cell) indicates a stoichiometric mixture.

However, the use of a wideband is a different story. The wideband utilizes an oxygen pump in feedback with a Nernst cell in order to maintain a stoich reading from the Nernst cell. However, the calibration curve, especially on the excess fuel (rich) side is significantly different for ethanol compared to gasoline. The reason for this is that the sensor reacts to a couple of the components that exist in the exhaust, and the partial pressures of these components will be different for different fuel blends. To use ethanol blends with a wideband requires a meter that allows you to enter the H/C (Hydrogen to Carbon) and O/C (Oxygen to Carbon) ratios. There is a chart I generated on the H/C and O/C ratios for different blends of ethanol to gas - see http://www.megasquirt.info/flexfuel.htm

If there is interest, I can go over in detail the chemical relationships (in plain english, I hope) to illustrate this, and how the wideband sensor operates specifically to ethanol. There is a lot of detail here: http://www.megasquirt.info/PWC/

- Bruce
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hotrod



Joined: 19 Apr 2005
Posts: 872
Location: Colorado

PostPosted: Wed Feb 15, 2006 11:10 pm    Post subject: Reply with quote

Very good info there, thanks for the addition to the board.

Your system looks like a good alternative for a lot of folks that deserves some investigation by those looking for a conversion option.

Quote:
If there is interest, I can go over in detail the chemical relationships (in plain english, I hope) to illustrate this, and how the wideband sensor operates specifically to ethanol.


That would be great background. It might also help the non-technical if you could give a representative example of how far the true value differes from the reported value. Sort of a cliff notes chart so folks can quickly get a feel for where they are when the see a specific value on a standard wideband.

What I'm thinking of is (when the reported value is 15% rich of stoich, the true mixture is xxxx) A couple data points like that or better yet a quick chart would be very useful for people to get a ball park number to shoot for to achieve a specific intended AFR.


Larry
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B.A.Bowling



Joined: 15 Feb 2006
Posts: 6
Location: Baltimore, MD

PostPosted: Sat Feb 18, 2006 3:38 pm    Post subject: Reply with quote

hotrod wrote:


That would be great background. It might also help the non-technical if you could give a representative example of how far the true value differes from the reported value. Sort of a cliff notes chart so folks can quickly get a feel for where they are when the see a specific value on a standard wideband.

Larry


I take a stab at it, the whole wideband thing can get complicated.

In simple language, the wideband sensor has a Nernst cell (simple language?) which indicates the presense of O2 by generating a voltage. There is also part of the sensor which can pump in or take away O2, known as a oxygen pump. The pump introduces or removes O2 in order to get the nernst voltage to be a certain value, say 0.45 volts. How much the oxygen pump is turned on, given by pump current, is converted into a air/fuel ratio reading.

Note that at the perfect combustion point, where all of the hydrocarbons are combined with all of the oxygen without any excess, there is no pump action. So, at stoich, the wideband should read the stoich AFR value. The wideband meter should be [most] accurate at stoich (but...).

The actual value of AFR depends on the hydrocarbon. For the case of gasoline and ethanol mix, the AFR stoich point moves (assume gasoline has H/C of 1.65, O/C=0):

100% gasoline = 14.191 AFR
90% gasoline, 10% ethanol = 13.667
50/50% mix = 11.569
15%gas, 85%ethanol = 9.773
100% ethanol = 8.946

The stoich point is also referred to a lambda value of 1.0 - lambda is just the actual mass air/fuel ratio divided by the mass air/fuel ratio at stoich. So, if the AFR reading is 11.35 and the stoich AFR is 14.191 then the lambda value is (11.35 / 14.191) = 0.8

This leads to the first problem with most wideband meters with fuels other than gas: no way of entering the stoich AFR value in order to shift the scale. Even if the meter reads in units of lambda, the calculated lambda value needs to know which type of hydrocarbon it is burning.

Now, at stoich, the hydrocarbon is comsumed during combustion to produce H2O and CO2 (perfect combustion). If the mixture is lean then there is leftover oxygen, and you will still get CO2 and H2O, but you will get minimal H2 and CO. If the mixture is rich then there will be no excess oxygen (it was all used up) but there will be the usual H2O and CO2, plus CO and H2. I am leaving out the NOx, unburned hydrocarbons, etc, to make things simple.

In other words, after combustion there will always be CO2 and H2O, and at stoich (perfect) this is what you get. If there is too little fuel (lean) there is excess oxygen. If there is too much fuel (rich) then there is CO and H2 formed.

Now, the question pops up: How much excess O2 (lean) or excess CO and H2 (rich) - how do you know? This depends on how far from stoich is the mix (either rich or lean) AND the composition of the hydrocarbon being burned. Both need to be known in order to determine lambda and/or AFR.

Gasoline (regular) is a hydrocarbon (i.e. hydrogen and carbon, or HC) is roughly H1.95 C. There are 1.95 H to one C (actually the atoms are whole, not a fraction..). Quite often, it is easier to think in ratios of hydrogen to carbon, also known as the H/C ratio, in this case H/C is 1.95.

Ethanol has a formula C2 H6 O, in this case the H/C ratio is 3, and there is also a O/C ratio of 0.5 (oxygen to carbon).

A mix of gasoline to ethanol will have a combined H, C, and O amount that depends on the mix. The H, C, and O content will drive the amount of excess O2 or excess H2 and CO - this is the reason why ethanol generates differences in exhaust emission output compared to gas.

How much? This can be calculated by accounting for all of the H,C, and O, combined with the O2 in the air before and after combustion. No magic here, nothing is created or destroyed, they just hook up in other forms. You "balance" the chemical equation before and after combustion. I will not go into how to balance the equation here (we can discuss this more if people are into the gory details), the take-away here is that the makeup of the hydrocarbon going in as well as the mass quantities of air to fuel both drive the composition of the exhaust.

Lets take a simple comparison:

On the lean side - excess oxygen, pick a lambda of 1.2. Compare 100% gas to 100% ethanol.

First, for 100% gas:
H/C ratio = 1.95, O/C ratio = 0, stoich AFR = 14.62, lambda = 1.2, AFR=17.5
--> results: O2 = 4.27% (molar)

For 100% ethanol:
H/C ratio = 3, O/C ratio = 0.5, stoich AFR = 8.95, lambda = 1.2, AFR = 10.74
--> results: O2 = 4.60% (molar)

So, on the lean side, there is not much of a difference.

Now, look at the rich side, which will produce CO and H2. The wideband sensor reacts to both of these with different sensitivities. In reality, the wideband sensor actually uses the oxygen generated by the oxygen pump in order to "complete combustion" according to the two relations:

2CO + O2 -> 2CO2
2H2 + O2 -> 2H2O

Run the numbers for a lambda of 0.8 (and a combustion temp of 1740K):

For 100% gas:
H/C ratio = 1.95, O/C ratio = 0, stoich AFR = 14.62, lambda = 0.8, AFR=11.70
--> results: CO = 6.57%, H2 = 2.63% (molar)

For 100% ethanol:
H/C ratio = 3, O/C ratio = 0.5, stoich AFR = 8.95, lambda = 0.8, AFR = 7.16
--> results: CO = 5.88%, H2 = 3.16% (molar)

The differences in molar percent (equivalant to partial pressure) is significant for CO and H2, and depending on the individual sensor sensitivities to these species the introduced error can be significant.

Also note that the farther away from stoich the mixture is, the more absolute error is introduced. This is why it is very hard to make a single correction factor number to apply to the meter reading, this correction depends on the gas/ethanol mix, if it is on the lean or rich side, the individual senstivities to O2, H2, and CO, and how far away from stoich is the mixture is. It also depends on the combustion temperature - something not show above is that the CO and H2 are calculated from a guess on the combustion temperature, using the "water-gas equilibrium".

And I have not even addressed that a small percent of unburned hydrocarbons will get through, and the sensor has a sensitivity to this as well, depending on the hydrocarbon. How much is a "small percentage"? Without direct measurement its hard to determine....
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hotrod



Joined: 19 Apr 2005
Posts: 872
Location: Colorado

PostPosted: Sat Feb 18, 2006 9:06 pm    Post subject: Reply with quote

Very interesting summary.

Thanks for all the work on that post.

Now the important points about wide band sensors I see are:

1. For practical purposes a stoich mixture reading can be assumed to be accurate for any common fuel mix.

2. With Gasoline / ethanol fuel blends on the lean side of stoich (the most important number due to lean combustion temperatures) your wide band errors will be small .

3. With Gasoline / ethanol fuel blends on the rich side of stoich the wideband will report mixtures which are too rich with the error increasing as you move farther from a stochiometric mixture.

4. The larger the ethanol fraction the higher the over-rich error will be.

In practical terms ---- while tuning gasoline ethanol blends ----- if your wide band reports a lean mixture, believe it.

If the wide band reports a rich mixture, you are probably not quite as rich as it looks. Do not lean out a rich mixture too much in one step, or you may end up leaner than is safe.


Larry
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B.A.Bowling



Joined: 15 Feb 2006
Posts: 6
Location: Baltimore, MD

PostPosted: Sun Feb 19, 2006 4:25 pm    Post subject: Reply with quote

Yep, Larry you got it right!

Added info: practically all of the wideband meters out there use the "default" response curve that was published in the LSU-4.2 datasheet to generate lambda (then AFR from this). Here is the curve:



It was generated assuming a H/C ratio of 2 and perfect combustion.

It is possible to use the pump current obtained from the meter (most will give this to you) and then make up your own curve. An easy way would be with an exhaust gas analyzer - many shops have this and may allow you to run a few points. Lean is easy, and will be just a scale factor (from stoich). Rich is a little tricker, but use the CO readings from the 5-gas to calibrate with a few points. Unfortunately you will not get a H2 reading, but the CO reading will help scale things to make the curve much better. Once you make up a new table of lambda (or equivalence ratios, for academic types) you can then be confident on the tune.

Of course, if you have access to a 5-gas, then it may be better to use this for the tune Smile. Just make absolutely sure that they set the H/C and O/C ratios in the meter (most will not even know these are there for setting), or the calculation (using Brettshneider) will be in error. In fact, 5-gas analyzers errors crop up all of the time if they assume regular pump gas but actually burning 10% ethanol (equiv) enriched...

- Bruce
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